A 100 mL solution was made by adding 1.43 g of Na₂CO₃.xH₂O. The normality of the solution is 0.1 N. The value of x is _____.

(The atomic mass of Na is 23 g/mol)

250 mL of a waste solution obtained from the workshop of a goldsmith contains 0.1 M AgNO₃ and 0.1 M AuCl. The solution was electrolyzed at 2V by passing a current of 1A for 15 minutes. The metal/metals electrodeposited will be

[ $$E_{A{g^ + }/Ag}^0$$ = 0.80 V, $$E_{A{u^ + }/Au}^0$$ = 1.69 V ]

The molecule in which hybrid MOs involve only one d-orbital of the central atom is :

The one that can exhibit highest paramagnetic behaviour among the following is :

gly = glycinato; bpy = 2, 2'-bipyridine