Given
$$E_{C{l_2}/C{l^ - }}^o$$ = 1.36 V, $$E_{C{r^{3 + }}/Cr}^o$$ = - 0.74 V
$$E_{C{r_2}{O_7}^{2 - }/C{r^{3 + }}}^o$$ = 1.33 V, $$E_{Mn{O_4}^ - /Mn ^{2+}}^o$$ = 1.51 V
Among the following, the strongest reducing agent is :

Two reactions R₁ and R₂ have identical pre-exponential factors. Activation energy of R₁ exceeds that of R₂ by 10 kJ mol^–1. If k₁ and k₂ are rate constants for reactions R₁ and R₂ respectively at 300 K, then ln(k₂/k₁) is equal to :
(R = 8.314 J mol^–1 K^–1)

The freezing point of benzene decreases by 0.45⁰C when 0.2 g of acetic acid is added to 20g of benzene. If acetic acid associates to form a dimer in benzene, percentage association of acetic acid in benzene will be: (K_f for benzene = 5.12 K kg mol^–1)

$$\Delta $$U is equal to :