Four successive members of the first row transition elements are listed below with atomic numbers. Which one of them is expected to have the highest $$E_{{M^{3 + }}/{M^{2 + }}}^0$$ value?

Given

$$E_{C{r^{2 + }}/Cr}^o$$ = -0.74 V; $$E_{MnO_4^ - /M{n^{2 + }}}^o$$ = 1.51 V

$$E_{C{r_2}O_7^{2 - }/C{r^{3 + }}}^o$$ = 1.33 V; $$E_{Cl/C{l^ - }}^o$$ = 1.36 V

Based on the data given above, strongest oxidising agent will be :

The molarity of a solution obtained by mixing 750 mL of 0.5 (M) HCl with 250 mL of 2(M) HCl will be:

A solution of (–$$l$$) – chloro –1 – phenylethane in toluene racemises slowly in the presence of a small amount of SbCl₅, due to the formation of :