1
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
Which of the following pairs represents linkage isomers ?
A
[Pd (P Ph3)2 (NCS)2] and [Pd (P Ph3)2 (SCN)2]
B
[Co(NH3)5 NO3]SO4 and [Co(NH3)5 SO4]NO3
C
[Pt Cl2(NH3)4] Br2 and [Pt Br2(NH3)4] Cl2
D
[Cu (NH3)4] [Pt Cl4] and [Pt (NH3)4] [CuCl4]
2
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
Knowing that the Chemistry of lanthanoids (Ln) is dominated by its +3 oxidation state, which of the following statements is incorrect?
A
Because of the large size of the Ln (III) ions the bonding in its compounds is predominantly ionic in character.
B
The ionic sizes of Ln (III) decrease in general with increasing atomic number.
C
Ln (III) compounds are generally colourless
D
Ln (III) hydroxides are mainly basic in character.
3
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
In context with the transition elements, which of the following statements is incorrect ?
A
In addition to the normal oxidation states, the zero oxidation state is also shown by these elements in complexes.
B
In the highest oxidation states, the transition metal show basic character and form cationic complexes.
C
In the highest oxidation states of the first five transition elements (Sc to Mn), all the 4s and 3d electrons are used for bonding
D
Once the d5 configuration is exceeded, the tendency to involve all the 3d electrons in bonding decreases.
4
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
The half life period of a first order chemical reaction is 6.93 minutes. The time required for the completion of 99% of the chemical reaction will be (log 2=0.301) :
A
230.3 minutes
B
23.03 minutes
C
46.06 minutes
D
460.6 minutes
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