1
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
In a fuel cell methanol is used as fuel and oxygen gas is used as an oxidizer. The reaction is
CH3OH(l) + 3/2O2 $$\to$$ CO2 (g) + 2H2O (l)
At 298K standard Gibb’s energies of formation for CH3OH(l), H2O(l) and CO2 (g) are -166.2, -237.2 and -394.4 kJ mol−1 respectively. If standard enthalpy of combustion of methanol is -726 kJ mol−1, efficiency of the fuel cell will be
A
87%
B
90%
C
97%
D
80%
2
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
Given : $$E_{F{e^{3 + }}/Fe}^o$$ = -0.036V; $$E_{F{e^{2 + }}/Fe}^o$$ = -0.439 V
The value of standard electrode potential for the change,
Fe3+ (aq) + e- $$\to$$ Fe2+ (aq) will be
A
-0.072 V
B
0.385 V
C
0.770 V
D
0.270
3
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
Using MO theory, predict which of the following species has the shortest bond length?
A
$$O_2^+$$
B
$$O_2^-$$
C
$$O_2^{2-}$$
D
$$O_2^{2+}$$
4
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
In which of the following arrangements, the sequence is not strictly according to the property written against it
A
CO2 < SiO2 < SnO2 < PbO2 : increasing oxidising power
B
HF < HCl < HBr, HI : increasing acid strength
C
NH3 < PH3 < AsH3 < SbH3 : increasing basic strength
D
B < C < O < N : increasing first ionization enthalpy
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