1
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
On the basis of the following thermochemical data :
($$\Delta _fG^oH^+_{(aq)}$$ = 0)

H2O(l) $$\to$$ H+(aq) + OH-(aq); $$\Delta H$$ = 57.32 kJ
H2(g) + $${1 \over 2} O_2(g) \to$$ H2O(l); $$\Delta H$$ = -286.20 kJ

The value of enthalpy of formation of OH ion at 25oC is :
A
-22.88 kJ
B
-228.88 kJ
C
+228.88 kJ
D
-343.52 kJ
2
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
A binary liquid solution is prepared by mixing n-heptane and ethanol. Which one of the following statements is correct regarding the behaviour of the solution ?
A
The solution formed is an ideal solution
B
The solution is non-ideal, showing +ve deviation from Raoult’s law.
C
The solution is non-ideal, showing –ve deviation from Raoult’s law.
D
n-heptane shows +ve deviation while ethanol shows –ve deviation from Raoult’s law.
3
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
The alkene that exhibits geometrical isomerism is :
A
propene
B
2-methyl propene
C
2-butene
D
2- methyl -2- butene
4
AIEEE 2009
MCQ (Single Correct Answer)
+4
-1
Arrange the carbanions, $${(C{H_3})_3}\overline C $$, $$\overline C C{l_3}$$ , $${(C{H_3})_2}\overline C H$$, $${C_6}{H_5}\overline C H{}_2$$ in order of their decreasing stability :
A
$${(C{H_3})_2}\overline C H$$ > $$\overline C C{l_3}$$ > $${C_6}{H_5}\overline C H{}_2$$ > $${(C{H_3})_3}\overline C $$
B
$$\overline C C{l_3}$$ > $${C_6}{H_5}\overline C H{}_2$$ > $${(C{H_3})_2}\overline C H$$ > $${(C{H_3})_3}\overline C $$
C
$${(C{H_3})_3}\overline C $$ > $${(C{H_3})_2}\overline C H$$ > $${C_6}{H_5}\overline C H{}_2$$ > $$\overline C C{l_3}$$
D
$${C_6}{H_5}\overline C H{}_2$$ > $$\overline C C{l_3}$$ > $${(C{H_3})_3}\overline C $$ > $${(C{H_3})_2}\overline C H$$

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