JEE Main 2025 (Online) 24th January Evening Shift | Thermodynamics Question 22 | Chemistry

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JEE Main 2025 (Online) 24th January Evening Shift

MCQ (Single Correct Answer)

-1

Which of the following mixing of 1 M base and 1 M acid leads to the largest increase in temperature?

50 mL HCl and 20 mL NaOH

30 mL HCl and 30 mL NaOH

$45 \mathrm{~mL} \mathrm{~CH}_3 \mathrm{COOH}$ and 25 mL NaOH

$30 \mathrm{~mL} \mathrm{~CH}_3 \mathrm{COOH}$ and 30 mL NaOH

JEE Main 2025 (Online) 24th January Morning Shift

MCQ (Single Correct Answer)

-1

Let us consider an endothermic reaction which is non-spontaneous at the freezing point of water. However, the reaction is spontaneous at boiling point of water. Choose the correct option.

Both $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ are (-ve)

$\Delta \mathrm{H}$ is $(+\mathrm{ve})$ but $\Delta \mathrm{S}$ is (-ve)

$\Delta \mathrm{H}$ is $(-\mathrm{ve})$ but $\Delta \mathrm{S}$ is (+ve)

Both $\Delta \mathrm{H}$ and $\Delta \mathrm{S}$ are (+ve)

JEE Main 2025 (Online) 23rd January Evening Shift

MCQ (Single Correct Answer)

-1

The effect of temperature on spontaneity of reactions are represented as :

	$\Delta$H	$\Delta$S	Temperature	Spontaneity
(A)	$+$	$-$	any T	Non spontaneous
(B)	$+$	$+$	low T	spontaneous
(C)	$-$	$-$	low T	Non spontaneous
(D)	$-$	$+$	any T	spontaneous

The incorrect combinations are :

(A) and (C) only

(B) and (D) only

(A) and (D) only

(B) and (C) only

JEE Main 2025 (Online) 23rd January Morning Shift

MCQ (Single Correct Answer)

-1

Ice at $-5^{\circ} \mathrm{C}$ is heated to become vapor with temperature of $110^{\circ} \mathrm{C}$ at atmospheric pressure. The entropy change associated with this process can be obtained from

$\int_{268 \mathrm{~K}}^{273 \mathrm{~K}} \mathrm{C}_{\mathrm{p}, \mathrm{m}} \mathrm{dT}+\frac{\Delta \mathrm{H}_{\mathrm{m}} \text {, fusion }}{\mathrm{T}_{\mathrm{f}}}+\frac{\Delta \mathrm{H}_{\mathrm{m}, \text { vaporisation }}}{\mathrm{T}_{\mathrm{b}}}+\int_{273 \mathrm{~K}}^{373 \mathrm{~K}} \mathrm{C}_{\mathrm{p}, \mathrm{m}} \mathrm{dT}+\int_{373 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}, \mathrm{m}} \mathrm{dT}$

$\int_{268 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}} \mathrm{dT}+\frac{\Delta \mathrm{H}_{\text {melting }}}{273}+\frac{\Delta \mathrm{H}_{\text {boiling }}}{373}$

$\int_{268 \mathrm{~K}}^{383 \mathrm{~K}} \mathrm{C}_{\mathrm{p}} \mathrm{dT}+\frac{\mathrm{q}_{\text {rev }}}{\mathrm{T}}$

$\int_{268 \mathrm{~K}}^{273 \mathrm{~K}} \frac{\mathrm{C}_{\mathrm{p}, \mathrm{m}}}{\mathrm{T}} \mathrm{dT}+\frac{\Delta \mathrm{H}_{\mathrm{m}}, \text { fusion }}{\mathrm{T}_{\mathrm{f}}}+\frac{\Delta \mathrm{H}_{\mathrm{m}, \text { vaporisation }}^{373 \mathrm{~K}}}{\mathrm{~T}_{\mathrm{b}}}+\int_{273 \mathrm{~K}} \frac{\mathrm{C}_{\mathrm{p}, \mathrm{m}} \mathrm{dT}}{T}+\int_{373 \mathrm{~K}}^{383 \mathrm{~K}} \frac{\mathrm{C}_{\mathrm{p}, \mathrm{m}} \mathrm{dT}}{\mathrm{T}}$

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