1
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
A reaction at 1 bar is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following :
A
Both $$\Delta $$H and $$\Delta $$S are negative.
B
Both $$\Delta $$H and $$\Delta $$S are positive.
C
$$\Delta $$H is positive while $$\Delta $$S is negative.
D
$$\Delta $$H is negative while $$\Delta $$S is positive.
2
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The plot shows the variation of −$$ln$$ Kp versus temperature for the two reactions.

M(s) + $${1 \over 2}$$ O2(g) $$ \to $$ MO(s) and

C(s) + $${1 \over 2}$$ O2(g) $$ \to $$ CO(s)

JEE Main 2016 (Online) 9th April Morning Slot Chemistry - Thermodynamics Question 163 English
Identify the correct statement :
A
At T > 1200 K, carbon will reduce MO(s) to M(s).
B
At T < 1200 K, the reaction

MO(s) + C(s) $$ \to $$ M(s) + CO(g) is spontaneous.
C
At T < 1200 K, oxidation of carbon is unfavourable
D
Oxidation of carbon is favourable at all temperatures.
3
JEE Main 2016 (Offline)
MCQ (Single Correct Answer)
+4
-1
Change Language
The heats of combustion of carbon and carbon monoxide are –393.5 and –283.5 kJ mol–1, respectively. The heat of formation (in kJ) of carbon monoxide per mole is :
A
676.5
B
-676.5
C
–110
D
110.5
4
JEE Main 2015 (Offline)
MCQ (Single Correct Answer)
+4
-1
Change Language
The following reaction is performed at 298 K
2NO(g) + O2 (g) $$\leftrightharpoons$$ 2NO2 (g)
The standard free energy of formation of NO(g) is 86.6 kJ/mol at 298 K. What is the standard free energy of formation of NO2(g) at 298 K? (KP = 1.6 × 1012)
A
86600 + R(298) ln(1.6 $$\times$$ 1012)
B
86600 - $$ln (1.6 \times 10^{12}) \over R (298)$$
C
0.5[2×86,600 – R(298) ln(1.6×1012)]
D
R(298) ln(1.6×1012) – 86600
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