Which of the following sequences of hybridisation, geometry and magnetic nature are correct for the given coordination compounds?

A. $\left[\mathrm{NiCl}_4\right]^{2-}-\mathrm{sp}^3$, tetrahedral, paramagnetic

B. $\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_6\right]^{2+}-\mathrm{sp}^3 \mathrm{~d}^2$, octahedral, paramagnetic

C. $\left[\mathrm{Ni}(\mathrm{CO})_4\right]-\mathrm{sp}^3$, tetrahedral, paramagnetic

D. $\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{2-}-\mathrm{dsp}^2$, square planar, diamagnetic

Choose the correct answer from the options given below :

Given below are two statements :

Statement I : A mixture of $\mathrm{C}_{12} \mathrm{H}_{22} \mathrm{O}_{11}$ (sugar) and NaCl can be separated by dissolving sugar in alcohol, due to differential solubility.

Statement II : Rose essence from rose petals is seperated by steam distillation due to its high volatility and insolubility in $\mathrm{H}_2 \mathrm{O}$.

In the light of the above statements, choose the correct answer from the options given below :

Shown below is the structure of methyl acetate with three different $\alpha, \beta$ and $\gamma$ carbon - oxygen bonds.

The correct order of bond lengths of these bonds is :

' $x$ ' is the product which is obtained by the hydrolysis of prop-1-yne in the presence of mercuric sulphate under dilute acidic medium at 333 K . ' $y$ ' is the product which is obtained by the reaction of ethane nitrile with methyl magnesium bromide in dry ether followed by hydrolysis. IUPAC name of product obtained from ' $x^{\prime}$ and ' $y$ ' in the presence of barium hydroxide followed by heating is :