Given below are two statements :

Statement I : The number of compounds among $\mathrm{SO}_2, \mathrm{SO}_3, \mathrm{SF}_4, \mathrm{SF}_6$ and $\mathrm{H}_2 \mathrm{~S}$ in which sulphur does not obey the Octet rule is 3 .

Statement II : Among $\left[\mathrm{H}_2 \mathrm{O}, \mathrm{ClF}_3, \mathrm{SF}_4\right],\left[\mathrm{NH}_3, \mathrm{BrF}_5, \mathrm{SF}_4\right],\left[\mathrm{BrF}_5, \mathrm{ClF}_3, \mathrm{XeF}_4\right]$ and [ $\mathrm{XeF}_4, \mathrm{ClF}_3, \mathrm{H}_2 \mathrm{O}$ ], the number of sets in which all the molecules have one lone pair of electrons on the central atom is 1 .

In the light of the above statements, choose the correct answer from the options given below :

Match List - I with List - II.

Given $V_1$ and $V_2$ are initial and final volumes respectively.

Choose the correct answer from the options given below :

Given below are two statements :

Statement I : $\quad \mathrm{H}_2 \mathrm{O}$ molecules move from the chamber 1 to chamber 2 .

Statement II : The osmotic pressure of a solution prepared by dissolving 50 mg of potassium sulphate (molar mass $=174 \mathrm{~g} / \mathrm{mol}$ ) in 2 L of water (at $27^{\circ} \mathrm{C}$ ) is 0.0107 bar. (Given: $\mathrm{R}=0.083 \mathrm{dm}^3$ bar $\mathrm{K}^{-1} \mathrm{~mol}^{-1}$ and assume complete dissociation of electrolyte)

In the light of the above statements, choose the correct answer from the options given below :

Given is a concentrated solution of a weak electrolyte $A_x B_y$ of concentration ' $c$ ' and dissociation constant ' K '. The degree of dissociation is given by :