1
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Given below are two statements :

Statement (I) : Kjeldahl method is applicable to estimate nitrogen in pyridine.

Statement (II) : The nitrogen present in pyridine can easily be converted into ammonium sulphate in Kjeldahl method.

In the light of the above statements, choose the correct answer from the options given below :

A
Both Statement I and Statement II are true
B
Both Statement I and Statement II are false
C
Statement I is true but Statement II is false
D
Statement I is false but Statement II is true
2
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

Identify the incorrect statements about group 15 elements :

(A) Dinitrogen is a diatomic gas which acts like an inert gas at room temperature.

(B) The common oxidation states of these elements are $$-3,+3$$ and +5.

(C) Nitrogen has unique ability to form $$\mathrm{p} \pi-\mathrm{p} \pi$$ multiple bonds.

(D) The stability of +5 oxidation states increases down the group.

(E) Nitrogen shows a maximum covalency of 6.

Choose the correct answer from the options given below :

A
(A), (C), (E) only
B
(D) and (E) only
C
(A), (B), (D) only
D
(B), (D), (E) only
3
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1

In qualitative test for identification of presence of phosphorous, the compound is heated with an oxidising agent. Which is further treated with nitric acid and ammonium molybdate respectively. The yellow coloured precipitate obtained is :

A
$$\mathrm{Na}_3 \mathrm{PO}_4 \cdot 12 \mathrm{MoO}_3$$
B
$$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \cdot 12\left(\mathrm{NH}_4\right)_2 \mathrm{MoO}_4$$
C
$$\mathrm{MoPO}_4 \cdot 21 \mathrm{NH}_4 \mathrm{NO}_3$$
D
$$\left(\mathrm{NH}_4\right)_3 \mathrm{PO}_4 \cdot 12 \mathrm{MoO}_3$$
4
JEE Main 2024 (Online) 8th April Evening Shift
Numerical
+4
-1

$$\Delta_{\text {vap }} \mathrm{H}^{\ominus}$$ for water is $$+40.79 \mathrm{~kJ} \mathrm{~mol}^{-1}$$ at 1 bar and $$100^{\circ} \mathrm{C}$$. Change in internal energy for this vapourisation under same condition is ________ $$\mathrm{kJ} \mathrm{~mol}^{-1}$$. (Integer answer) (Given $$\mathrm{R}=8.3 \mathrm{~JK}^{-1} \mathrm{~mol}^{-1}$$)

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