Lead storage battery contains $38 \%$ by weight solution of $\mathrm{H}_{2} \mathrm{SO}_{4}$. The van't Hoff factor is $2.67$ at this concentration. The temperature in Kelvin at which the solution in the battery will freeze is ________. (Nearest integer).

Given $\mathrm{K}_{f}=1.8 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Iron oxide FeO, crystallises in a cubic lattice with a unit cell edge length of 5.0 Å. If density of the $\mathrm{FeO}$ in the crystal is $4.0 \mathrm{~g} \mathrm{~cm}^{-3}$, then the number of $\mathrm{FeO}$ units present per unit cell is __________. (Nearest integer)

Given: Molar mass of $\mathrm{Fe}$ and $\mathrm{O}$ is 56 and $16 \mathrm{~g} \mathrm{~mol}^{-1}$ respectively. $\mathrm{N}_{\mathrm{A}}=6.0 \times 10^{23} \mathrm{~mol}^{-1}$

A vector $\vec{v}$ in the first octant is inclined to the $x$-axis at $60^{\circ}$, to the $y$-axis at 45 and to the $z$-axis at an acute angle. If a plane passing through the points $(\sqrt{2},-1,1)$ and $(a, b, c)$, is normal to $\vec{v}$, then :

Let $a_{1}=1, a_{2}, a_{3}, a_{4}, \ldots .$. be consecutive natural numbers.

Then $\tan ^{-1}\left(\frac{1}{1+a_{1} a_{2}}\right)+\tan ^{-1}\left(\frac{1}{1+a_{2} a_{3}}\right)+\ldots . .+\tan ^{-1}\left(\frac{1}{1+a_{2021} a_{2022}}\right)$ is equal to :