Consider the following equation:

$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g), \Delta H=-190 \mathrm{~kJ}$

The number of factors which will increase the yield of $\mathrm{SO}_{3}$ at equilibrium from the following is _______.

A. Increasing temperature

B. Increasing pressure

C. Adding more $\mathrm{SO}_{2}$

D. Adding more $\mathrm{O}_{2}$

E. Addition of catalyst

Lead storage battery contains $38 \%$ by weight solution of $\mathrm{H}_{2} \mathrm{SO}_{4}$. The van't Hoff factor is $2.67$ at this concentration. The temperature in Kelvin at which the solution in the battery will freeze is ________. (Nearest integer).

Given $\mathrm{K}_{f}=1.8 \mathrm{~K} \mathrm{~kg} \mathrm{~mol}^{-1}$

Let $a_{1}=1, a_{2}, a_{3}, a_{4}, \ldots .$. be consecutive natural numbers.

Then $\tan ^{-1}\left(\frac{1}{1+a_{1} a_{2}}\right)+\tan ^{-1}\left(\frac{1}{1+a_{2} a_{3}}\right)+\ldots . .+\tan ^{-1}\left(\frac{1}{1+a_{2021} a_{2022}}\right)$ is equal to :

For $\alpha, \beta \in \mathbb{R}$, suppose the system of linear equations

$$ \begin{aligned} & x-y+z=5 \\ & 2 x+2 y+\alpha z=8 \\ & 3 x-y+4 z=\beta \end{aligned} $$

has infinitely many solutions. Then $\alpha$ and $\beta$ are the roots of :