4.0 moles of argon and 5.0 moles of PCl₅ are introduced into an evacuated flask of 100 litre capacity at 610 K. The system is allowed to equilibrate. At equilibrium, the total pressure of mixture was found to be 6.0 atm. The K_p for the reaction is :

[Given : R = 0.082 L atm K^$$-$$1 mol^$$-$$1]

Given below are two statements. One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : The first ionization enthalpy for oxygen is lower than that of nitrogen.

Reason R : The four electrons in 2p orbitals of oxygen experience more electron-electron repulsion.

In the light of the above statements, choose the correct answer from the options given below.

Given below are two statements.

$$\bullet$$ Statement I : In CuSO₄ . 5H₂O, Cu-O bonds are present.

$$\bullet$$ Statement II : In CuSO₄ . 5H₂O, ligands coordinating with Cu(II) ion are O-and S-based ligands.

In the light of the above statements, choose the correct answer from the options given below.

Number of lone pair(s) of electrons on central atom and the shape BrF₃ molecule respectively, are