The reaction, MgO(s) + C(s) $$ \to $$ Mg(s) + CO(g), for which $$\Delta $$_rH^o + 491.1 kJ mol^–1 and $$\Delta $$_rS^o = 198.0 JK^–1 mol^–1, is not feasible at 298 K. Temperature above which reaciton will be feasible is :

$$\underline A \,\,\buildrel {4KOH,{O_2}} \over \longrightarrow \,\,\mathop {2\underline B }\limits_{\left( {Green} \right)} \,\, + \,\,2{H_2}O$$

$$3\underline B \,\,\buildrel {4HCl} \over \longrightarrow \,\,\mathop {2\underline C }\limits_{\left( {Purple} \right)} \,\, + \,\,Mn{O_2} + 2{H_2}O$$

$$2\underline C \,\,\buildrel {{H_2}O.KI} \over \longrightarrow \,\,\mathop {2\underline A }\limits_{\left( {Purple} \right)} \,\, + \,\,2KOH\,\, + \,\,\underline D $$

In the above sequence of reactions, $${\underline A }$$ and $${\underline D }$$, respectively, are :

The reaction that does NOT define calcination is :

25 ml of the given HCl solution requires 30 mL of 0.1 M sodium carbonate solution. What is the volume of this HCl solution required to titrate 30 mL of 0.2 M aqueous NaOH solutions ?