1
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step process shown below :

O3(g) + Cl$${^ \bullet }$$ (g) $$ \to $$ O2(g) + ClO$${^ \bullet }$$ (g) . . . . . .(i)

ki = 5.2 × 109 L mol−1 s−1

ClO$${^ \bullet }$$(g) + O$${^ \bullet }$$(g) $$ \to $$ O2(g) + Cl$${^ \bullet }$$ (g) . . . . . . (ii)

kii = 2.6 × 1010 L mol−1 s−1

The closest rate constant for the overall reaction O3(g) + O$${^ \bullet }$$ (g) $$ \to $$ 2 O2(g) is :
A
5.2 × 109 L mol−1 s−1
B
2.6 × 1010 L mol−1 s−1
C
3.1 × 1010 L mol−1 s−1
D
1.4 × 1020 L mol−1 s−1
2
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
A reaction at 1 bar is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following :
A
Both $$\Delta $$H and $$\Delta $$S are negative.
B
Both $$\Delta $$H and $$\Delta $$S are positive.
C
$$\Delta $$H is positive while $$\Delta $$S is negative.
D
$$\Delta $$H is negative while $$\Delta $$S is positive.
3
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
What will occur if a block of copper metal is dropped into a beaker containing a solution of 1M ZnSO4?
A
The copper metal will dissolve and zinc metal will be deposited.
B
The copper metal will dissolve with evolution of hydrogen gas.
C
The copper metal will dissolve with evolution of oxygen gas.
D
No reaction will occur.
4
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The total number of orbitals associated with the principal quantum number 5 is :
A
5
B
10
C
20
D
25
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