1
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
A reaction at 1 bar is non-spontaneous at low temperature but becomes spontaneous at high temperature. Identify the correct statement about the reaction among the following :
A
Both $$\Delta $$H and $$\Delta $$S are negative.
B
Both $$\Delta $$H and $$\Delta $$S are positive.
C
$$\Delta $$H is positive while $$\Delta $$S is negative.
D
$$\Delta $$H is negative while $$\Delta $$S is positive.
2
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The group of molecules having identical shape is :
A
SF4 , XeF4 , CCl4
B
ClF3 , XeOF2 , XeF$$_3^ + $$
C
BF3 , PCl3 , XeO3
D
PCl5 , IF5 , XeO2F2
3
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The non-metal that does not exhibit positive oxidation state is :
A
Oxygen
B
Iodine
C
Chlorine
D
Fluorine
4
JEE Main 2016 (Online) 9th April Morning Slot
MCQ (Single Correct Answer)
+4
-1
Change Language
The reaction of ozone with oxygen atoms in the presence of chlorine atoms can occur by a two step process shown below :

O3(g) + Cl$${^ \bullet }$$ (g) $$ \to $$ O2(g) + ClO$${^ \bullet }$$ (g) . . . . . .(i)

ki = 5.2 × 109 L mol−1 s−1

ClO$${^ \bullet }$$(g) + O$${^ \bullet }$$(g) $$ \to $$ O2(g) + Cl$${^ \bullet }$$ (g) . . . . . . (ii)

kii = 2.6 × 1010 L mol−1 s−1

The closest rate constant for the overall reaction O3(g) + O$${^ \bullet }$$ (g) $$ \to $$ 2 O2(g) is :
A
5.2 × 109 L mol−1 s−1
B
2.6 × 1010 L mol−1 s−1
C
3.1 × 1010 L mol−1 s−1
D
1.4 × 1020 L mol−1 s−1
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