JEE Main Ultimate Online Test Series - 2027
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$$ \text { Match the LIST-I with LIST-II } $$
| List-I Thermodynamic Process | List-II Magnitude in kJ | ||
| A. | Work done in reversible, isothermal expansion of 2 mol of ideal gas from |
I. | 4 |
| B. | Work done in irreversible isothermal expansion of 1 mol ideal gas from |
II. | 11.5 |
| C. | Change in internal energy for adiabatic expansion of a 1 mol ideal gas with change of temperature |
III. | 6 |
| D. | Change in enthalpy at constant pressure of 1 mol ideal gas with change of temperature |
IV. | 7 |
Consider the following data :
$\Delta_{f}H^{\circ}$ (methane, g) = $-X \; \text{kJ mol}^{-1}$
Enthalpy of sublimation of graphite = $Y \; \text{kJ mol}^{-1}$
Dissociation enthalpy of $H_2 = Z \; \text{kJ mol}^{-1}$
The bond enthalpy of C–H bond is given by :
Which of the following graphs between pressure ' p ' versus volume ' V ' represents the maximum work done?
For the reaction, $\mathrm{N}_2 \mathrm{O}_4 \rightleftharpoons 2 \mathrm{NO}_2$, graph is plotted as shown below. Identify correct statements.
A. Standard free energy change for the reaction is $-5.40 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
B. As $\Delta \mathrm{G}^{\ominus}$ in graph is positive, $\mathrm{N}_2 \mathrm{O}_4$ will not dissociate into $\mathrm{NO}_2$ at all.
C. Reverse reaction will go to completion.
D. When 1 mole of $\mathrm{N}_2 \mathrm{O}_4$ changes into equilibrium mixture, value of $\Delta \mathrm{G}^{\ominus}=-0.84 \mathrm{~kJ} \mathrm{~mol}^{-1}$
E. When 2 mole of $\mathrm{NO}_2$ changes into equilibrium mixture, $\Delta \mathrm{G}^{\ominus}$ for equilibrium mixture is $-6.24 \mathrm{~kJ} \mathrm{~mol}^{-1}$.
Choose the correct answer from the options given below :
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