1
JEE Main 2025 (Online) 23rd January Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Which of the following happens when $\mathrm{NH}_4 \mathrm{OH}$ is added gradually to the solution containing 1 M $\mathrm{A}^{2+}$ and $1 \mathrm{M} \mathrm{B}^{3+}$ ions?

Given : $\mathrm{K}_{\text {sp }}\left[\mathrm{A}(\mathrm{OH})_2\right]=9 \times 10^{-10}$ and $\mathrm{K}_{\mathrm{sp}}\left[\mathrm{B}(\mathrm{OH})_3\right]=27 \times 10^{-18}$ at 298 K.

A
$\mathrm{A}(\mathrm{OH})_2$ will precipitate before $\mathrm{B}(\mathrm{OH})_3$
B
$\mathrm{A}(\mathrm{OH})_2$ and $\mathrm{B}(\mathrm{OH})_3$ will precipitate together
C
Both $\mathrm{A}(\mathrm{OH})_2$ and $\mathrm{B}(\mathrm{OH})_3$ do not show precipitation with $\mathrm{NH}_4 \mathrm{OH}$
D
$\mathrm{B}(\mathrm{OH})_3$ will precipitate before $\mathrm{A}(\mathrm{OH})_2$
2
JEE Main 2025 (Online) 22nd January Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The molar solubility(s) of zirconium phosphate with molecular formula $\left(\mathrm{Zr}^{4+}\right)_3\left(\mathrm{PO}_4^{3-}\right)_4$ is given by relation :

A
$\left(\frac{\mathrm{K}_{\mathrm{sp}}}{5348}\right)^{\frac{1}{6}}$
B
$\left(\frac{\mathrm{K}_{\mathrm{sp}}}{8435}\right)^{\frac{1}{7}}$
C
$\left(\frac{K_{s p}}{6912}\right)^{\frac{1}{7}}$
D
$\left(\frac{\mathrm{K}_{\mathrm{sp}}}{9612}\right)^{\frac{1}{3}}$
3
JEE Main 2024 (Online) 9th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

For a sparingly soluble salt $$\mathrm{AB}_2$$, the equilibrium concentrations of $$\mathrm{A}^{2+}$$ ions and $$B^{-}$$ ions are $$1.2 \times 10^{-4} \mathrm{M}$$ and $$0.24 \times 10^{-3} \mathrm{M}$$, respectively. The solubility product of $$\mathrm{AB}_2$$ is :

A
$$0.069 \times 10^{-12}$$
B
$$0.276 \times 10^{-12}$$
C
$$6.91 \times 10^{-12}$$
D
$$27.65 \times 10^{-12}$$
4
JEE Main 2024 (Online) 8th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement (I) : A Buffer solution is the mixture of a salt and an acid or a base mixed in any particular quantities

Statement (II) : Blood is naturally occurring buffer solution whose $$\mathrm{pH}$$ is maintained by $$\mathrm{H}_2 \mathrm{CO}_3 / \mathrm{HCO}_3{ }^{\ominus}$$ concentrations.

In the light of the above statements, choose the correct answer from the options given below :

A
Both Statement I and Statement II are false
B
Both Statement I and Statement II are true
C
Statement I is false but Statement II is true
D
Statement I is true but Statement II is false
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