40 mL of a mixture of $\mathrm{CH}_3 \mathrm{COOH}$ and HCl (aqueous solution) is titrated against 0.1 M NaOH solution conductometrically. Which of the following statement is correct?

If equal volumes of $A B_2$ and $X Y$ (both are salts) aqueous solutions are mixed, which of the following combination will give a precipitate of $\mathrm{AY}_2$ at 300 K ? (Given $\mathrm{K}_{\mathrm{sp}}\left(\right.$ at 300 K ) for $\mathrm{AY}_2=5.2 \times 10^{-7}$ )
Arrange the following in increasing order of solubility product :
$\mathrm{Ca}(\mathrm{OH})_2, \mathrm{AgBr}, \mathrm{PbS}, \mathrm{HgS}$
A weak acid HA has degree of dissociation x . Which option gives the correct expression of ( pH - $\mathrm{pK}_{\mathrm{a}}$)?
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