1
JEE Main 2023 (Online) 12th April Morning Shift
Numerical
+4
-1
Change Language

The reaction $$2 \mathrm{NO}+\mathrm{Br}_{2} \rightarrow 2 \mathrm{NOBr}$$

takes places through the mechanism given below:

$$\mathrm{NO}+\mathrm{Br}_{2} \Leftrightarrow \mathrm{NOBr}_{2}$$ (fast)

$$\mathrm{NOBr}_{2}+\mathrm{NO} \rightarrow 2 \mathrm{NOBr}$$ (slow)

The overall order of the reaction is ___________.

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2
JEE Main 2023 (Online) 11th April Morning Shift
Numerical
+4
-1
Change Language

$$\mathrm{KClO}_{3}+6 \mathrm{FeSO}_{4}+3 \mathrm{H}_{2} \mathrm{SO}_{4} \rightarrow \mathrm{KCl}+3 \mathrm{Fe}_{2}\left(\mathrm{SO}_{4}\right)_{3}+3 \mathrm{H}_{2} \mathrm{O}$$

The above reaction was studied at $$300 \mathrm{~K}$$ by monitoring the concentration of $$\mathrm{FeSO}_{4}$$ in which initial concentration was $$10 \mathrm{M}$$ and after half an hour became 8.8 M. The rate of production of $$\mathrm{Fe}_{2}\left(\mathrm{SO}_{4}\right)_{3}$$ is _________ $$\times 10^{-6} \mathrm{~mol} \mathrm{~L} \mathrm{~s}^{-1}$$ (Nearest integer)

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3
JEE Main 2023 (Online) 10th April Evening Shift
Numerical
+4
-1
Change Language

The number of incorrect statement/s from the following is ___________

A. The successive half lives of zero order reactions decreases with time.

B. A substance appearing as reactant in the chemical equation may not affect the rate of reaction

C. Order and molecularity of a chemical reaction can be a fractional number

D. The rate constant units of zero and second order reaction are $$\mathrm{mol} ~\mathrm{L}^{-1} \mathrm{~s}^{-1}$$ and $$\mathrm{mol}^{-1} \mathrm{~L} \mathrm{~s}^{-1}$$ respectively

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4
JEE Main 2023 (Online) 10th April Morning Shift
Numerical
+4
-1
Change Language

A molecule undergoes two independent first order reactions whose respective half lives are 12 min and 3 min. If both the reactions are occurring then the time taken for the 50% consumption of the reactant is ___________ min. (Nearest integer)

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