1
JEE Main 2022 (Online) 27th July Morning Shift
Numerical
+4
-1

$$2 \mathrm{NO}+2 \mathrm{H}_{2} \rightarrow \mathrm{N}_{2}+2 \mathrm{H}_{2} \mathrm{O}$$

The above reaction has been studied at $$800^{\circ} \mathrm{C}$$. The related data are given in the table below

Reaction serial number Initial Pressure of $${H_2}/kPa$$ Initial Pressure of $$NO/kPa$$ Initial rate $$\left( {{{ - dp} \over {dt}}} \right)/(kPa/s)$$
1 65.6 40.0 0.135
2 65.6 20.1 0.033
3 38.6 65.6 0.214
4 19.2 65.6 0.106

The order of the reaction with respect to NO is ___________.

2
JEE Main 2022 (Online) 26th July Morning Shift
Numerical
+4
-1

For a reaction $$\mathrm{A} \rightarrow 2 \mathrm{~B}+\mathrm{C}$$ the half lives are $$100 \mathrm{~s}$$ and $$50 \mathrm{~s}$$ when the concentration of reactant $$\mathrm{A}$$ is $$0.5$$ and $$1.0 \mathrm{~mol} \mathrm{~L}^{-1}$$ respectively. The order of the reaction is ______________ . (Nearest Integer)

3
JEE Main 2022 (Online) 25th July Evening Shift
Numerical
+4
-1

For the decomposition of azomethane.

CH3N2CH3(g) $$\to$$ CH3CH3(g) + N2(g), a first order reaction, the variation in partial pressure with time at 600 K is given as

The half life of the reaction is __________ $$\times$$ 10$$-$$5 s. [Nearest integer]

4
JEE Main 2022 (Online) 25th July Morning Shift
Numerical
+4
-1

The half life for the decomposition of gaseous compound $$\mathrm{A}$$ is $$240 \mathrm{~s}$$ when the gaseous pressure was 500 Torr initially. When the pressure was 250 Torr, the half life was found to be $$4.0$$ min. The order of the reaction is ______________. (Nearest integer)

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