Prolonged heating is avoided during the preparation of ferrous ammonium sulphate to :

Which of the following statements are correct?

(A) The M$$^{3+}$$/M$$^{2+}$$ reduction potential for iron is greater than manganese.

(B) The higher oxidation states of first row d-block elements get stabilized by oxide ion.

(C) Aqueous solution of Cr$$^{2+}$$ can liberate hydrogen from dilute acid.

(D) Magnetic moment of V$$^{2+}$$ is observed between 4.4 - 5.2 BM.

Choose the correct answer from the options given below :

Which halogen is known to cause the reaction given below :

$$2 \mathrm{Cu}^{2+}+4 \mathrm{X}^{-} \rightarrow \mathrm{Cu}_{2} \mathrm{X}_{2}(\mathrm{s})+\mathrm{X}_{2}$$

In chromyl chloride, the number of d-electrons present on chromium is same as in

(Given at no. of $$\mathrm{Ti}: 22, \mathrm{~V}: 23, \mathrm{Cr}: 24, \mathrm{Mn}: 25, \mathrm{Fe}: 26$$ )