1
JEE Main 2022 (Online) 27th July Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

In neutral or alkaline solution, $$\mathrm{MnO}_{4}^{-}$$ oxidises thiosulphate to :

A
$$\mathrm{S}_{2} \mathrm{O}_{7}^{2-}$$
B
$$\mathrm{S}_{2} \mathrm{O}_{8}^{2-}$$
C
$$\mathrm{SO}_{3}^{2-}$$
D
$$\mathrm{SO}_{4}^{2-}$$
2
JEE Main 2022 (Online) 27th July Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements.

Statement I : Iron (III) catalyst, acidified $$\mathrm{K}_{2} \mathrm{Cr}_{2} \mathrm{O}_{7}$$ and neutral $$\mathrm{KMnO}_{4}$$ have the ability to oxidise $$\mathrm{I}^{-}$$ to $$\mathrm{I}_{2}$$ independently.

Statement II : Manganate ion is paramagnetic in nature and involves $$\mathrm{p} \pi-\mathrm{p} \pi$$ bonding.

In the light of the above statements, choose the correct answer from the options given below.

A
Both Statement I and Statement II are true.
B
Both Statement I and Statement II are false.
C
Statement I is true but Statement II is false.
D
Statement I is false but Statement II is true.
3
JEE Main 2022 (Online) 27th July Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The total number of $$\mathrm{Mn}=\mathrm{O}$$ bonds in $$\mathrm{Mn}_{2} \mathrm{O}_{7}$$ is __________.

A
4
B
5
C
6
D
3
4
JEE Main 2022 (Online) 26th July Morning Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

The dark purple colour of $$\mathrm{KMnO}_{4}$$ disappears in the titration with oxalic acid in acidic medium. The overall change in the oxidation number of manganese in the reaction is :

A
5
B
1
C
7
D
2
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