Given below are two statements :

Statement I : Nickel is being used as the catalyst for producing syn gas and edible fats.

Statement II : Silicon forms both electron rich and electron deficient hydrides.

In the light of the above statements, choose the most appropriate answer from the options given below :

The set of correct statements is :

(i) Manganese exhibits +7 oxidation state in its oxide.

(ii) Ruthenium and Osmium exhibit +8 oxidation in their oxides.

(iii) Sc shows +4 oxidation state which is oxidizing in nature.

(iv) Cr shows oxidising nature in +6 oxidation state.

An indicator 'X' is used for studying the effect of variation in concentration of iodide on the rate of reaction of iodide ion with $$\mathrm{H_2O_2}$$ at room temp. The indicator 'X' forms blue coloured complex with compound 'A' present in the solution. The indicator 'X' and compound 'A' respectively are :

A chloride salt solution acidified with dil.HNO$$_3$$ gives a curdy white precipitate, [A], on addition of AgNO$$_3$$. [A] on treatment with NH$$_4$$OH gives a clear solution B. A and B are respectively :