Complete combustion of $X$ g of an organic compound gave $0.25$ g of $CO_2$ and $0.12$ g of $H_2O$. If the % of carbon is $25\%$ and of hydrogen is $4.89\%$, then $X = \underline{\phantom{xxx}} \times 10^{-3}$ g. (Nearest integer)

(Molar mass of C, H and O are 12, 1 and 16 g mol$^{-1}$ respectively.)

Given below are two statements :

Statement (I) : 1,2,3-Trihydroxypropane can be separated from water by simple distillation.

Statement (II) : An azeotropic mixture cannot be separated by fractional distillation.

In the light of the above statements, choose the correct answer from the options given below :

Match List - I with List - II.

Choose the correct answer from the options given below :

A student has been given 0.314 g of an organic compound and asked to estimate Sulphur. During the experiment, the student has obtained 0.4813 g of barium sulphate. The percentage of sulphur present in the compound is _________. (Given Molar mass in g mol⁻¹ S: 32, BaSO₄: 233)