In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of :

An inorganic Compound 'X' on treatment with concentrated H₂SO₄ produces brown fumes and gives dark brown ring with FeSO₄ in presence of concentrated H₂SO₄. Also Compound 'X' gives precipitate 'Y', when its solution in dilute HCl is treated with H₂S gas. The precipitate 'Y' on treatment with concentrated HNO₃ followed by excess of NH₄OH further gives deep blue coloured solution, Compound 'X' is :

Reagent, 1-napthylamine and sulphanilic acid in acetic acid is used for the detection of

Match List - I with List - II :

	List - I Test/Reagents/Observation(s)		List - II Species detected
(a)	Lassaigne's Test	(i)	Carbon
(b)	Cu(II) oxide	(ii)	Sulphur
(c)	Silver nitrate	(iii)	N, S, P, and halogen
(d)	The sodium fusion extract gives black precipitate with acetic acid and lead acetate	(iv)	Halogen Specifically

The correct match is :