Given below are two statements:

Statement I : Aqueous solution of K$$_2$$Cr$$_2$$O$$_7$$ is preferred as a primary standard in volumetric analysis over Na$$_2$$Cr$$_2$$O$$_7$$ aqueous solution.

Statement II : K$$_2$$Cr$$_2$$O$$_7$$ has a higher solubility in water than Na$$_2$$Cr$$_2$$O$$_7$$.

In the light of the above statements, choose the correct answer from the options given below:

A compound '$$\mathrm{X}$$' when treated with phthalic anhydride in presence of concentrated $$\mathrm{H}_{2} \mathrm{SO}_{4}$$ yields '$$\mathrm{Y}$$'. '$$\mathrm{Y}$$' is used as an acid/base indicator. '$$\mathrm{X}$$' and '$$\mathrm{Y}$$' are respectively

Given below are two statements:

Statement I : Methyl orange is a weak acid.

Statement II : The benzenoid form of methyl orange is more intense/deeply coloured than the quinonoid form.

In the light of the above statement, choose the most appropriate answer from the options given below:

Formation of which complex, among the following, is not a confirmatory test of $$\mathrm{Pb}^{2+}$$ ions :