Which one of the following complexes is violet in colour?

In Carius method, halogen containing organic compound is heated with fuming nitric acid in the presence of :

An inorganic Compound 'X' on treatment with concentrated H₂SO₄ produces brown fumes and gives dark brown ring with FeSO₄ in presence of concentrated H₂SO₄. Also Compound 'X' gives precipitate 'Y', when its solution in dilute HCl is treated with H₂S gas. The precipitate 'Y' on treatment with concentrated HNO₃ followed by excess of NH₄OH further gives deep blue coloured solution, Compound 'X' is :

Reagent, 1-napthylamine and sulphanilic acid in acetic acid is used for the detection of