Given below are two statements :

Statement I : The number of pairs among $\left[\mathrm{Al}_2 \mathrm{O}_3, \mathrm{Cr}_2 \mathrm{O}_3\right],\left[\mathrm{Cl}_2 \mathrm{O}_7, \mathrm{Mn}_2 \mathrm{O}_7\right],\left[\mathrm{Na}_2 \mathrm{O}, \mathrm{V}_2 \mathrm{O}_3\right]$ and $\left[\mathrm{CO}, \mathrm{N}_2 \mathrm{O}\right]$ that contain oxides of same nature (acidic, basic, neutral or amphoteric) is 4 .

Statement II : Among $\mathrm{Na}_2 \mathrm{O}, \mathrm{Al}_2 \mathrm{O}_3, \mathrm{CO}$ and $\mathrm{Cl}_2 \mathrm{O}_7$, the most basic and acidic oxides are $\mathrm{Na}_2 \mathrm{O}$ and $\mathrm{Cl}_2 \mathrm{O}_7$, respectively.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements :

Statement I: Aluminium upon reaction with NaOH forms $\left[\mathrm{Al}(\mathrm{OH})_6\right]^{3-}$ ion.

Statement II : The geometry of $\mathrm{ICl}_4^{-}, \mathrm{ClO}_3^{-}$and $\mathrm{IBr}_2^{-}$is square planar, pyramidal and linear respectively.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements :

Statement I : Presence of large number of unpaired electrons in transition metal atoms results in higher enthalpies of their atomisation.

Statement II : $\quad \mathrm{d}_{x y}=\mathrm{d}_{x z}=\mathrm{d}_{y z}<\mathrm{d}_{x^2-y^2}=\mathrm{d}_{z^2}$ and $\mathrm{d}_{x^2-y^2}=\mathrm{d}_{z^2}<\mathrm{d}_{x y}=\mathrm{d}_{x z}=\mathrm{d}_{y z}$ are the d-orbital splittings in $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ and $\left[\mathrm{Ni}(\mathrm{Cl})_4\right]^{2-}$ complex ions respectively.

In the light of the above statements, choose the correct answer from the options given below :

Identify the correct statements from the following

A. $\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ is the most stable complex among $\left[\mathrm{Fe}(\mathrm{OH})_6\right]^{3-},\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ and $\left[\mathrm{Fe}(\mathrm{SCN})_6\right]^{3-}$

B. The stability of $\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}$ is greater than that of $\left[\mathrm{Cu}(\mathrm{en})_2\right]^{2+}$

C. The hybridization of Fe in $\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$ is $\mathrm{d}^2 \mathrm{sp}^3$

D. $\left[\mathrm{Fe}\left(\mathrm{NO}_2\right)_3 \mathrm{Cl}_3\right]^{3-}$ exhibits linkage isomerism

E. $ \mathrm{NO}_2^{-}$and $\mathrm{SCN}^{-}$ligands are NOT ambidentate ligands

Choose the correct answer from the options given below :