1
JEE Main 2026 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement I: Aluminium upon reaction with NaOH forms $\left[\mathrm{Al}(\mathrm{OH})_6\right]^{3-}$ ion.

Statement II : The geometry of $\mathrm{ICl}_4^{-}, \mathrm{ClO}_3^{-}$and $\mathrm{IBr}_2^{-}$is square planar, pyramidal and linear respectively.

In the light of the above statements, choose the correct answer from the options given below :

A

Both Statement I and Statement II are true

B

Both Statement I and Statement II are false

C

Statement I is true but Statement II is false

D

Statement I is false but Statement II is true

2
JEE Main 2026 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Given below are two statements :

Statement I : Presence of large number of unpaired electrons in transition metal atoms results in higher enthalpies of their atomisation.

Statement II : $\quad \mathrm{d}_{x y}=\mathrm{d}_{x z}=\mathrm{d}_{y z}<\mathrm{d}_{x^2-y^2}=\mathrm{d}_{z^2}$ and $\mathrm{d}_{x^2-y^2}=\mathrm{d}_{z^2}<\mathrm{d}_{x y}=\mathrm{d}_{x z}=\mathrm{d}_{y z}$ are the d-orbital splittings in $\left[\mathrm{Fe}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{3+}$ and $\left[\mathrm{Ni}(\mathrm{Cl})_4\right]^{2-}$ complex ions respectively.

In the light of the above statements, choose the correct answer from the options given below :

A

Both Statement I and Statement II are correct

B

Both Statement I and Statement II are incorrect

C

Statement I is correct but Statement II is incorrect

D

Statement I is incorrect but Statement II is correct

3
JEE Main 2026 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

Identify the correct statements from the following

A. $\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ is the most stable complex among $\left[\mathrm{Fe}(\mathrm{OH})_6\right]^{3-},\left[\mathrm{Fe}\left(\mathrm{C}_2 \mathrm{O}_4\right)_3\right]^{3-}$ and $\left[\mathrm{Fe}(\mathrm{SCN})_6\right]^{3-}$

B. The stability of $\left[\mathrm{Cu}\left(\mathrm{NH}_3\right)_4\right]^{2+}$ is greater than that of $\left[\mathrm{Cu}(\mathrm{en})_2\right]^{2+}$

C. The hybridization of Fe in $\mathrm{K}_4\left[\mathrm{Fe}(\mathrm{CN})_6\right]$ is $\mathrm{d}^2 \mathrm{sp}^3$

D. $\left[\mathrm{Fe}\left(\mathrm{NO}_2\right)_3 \mathrm{Cl}_3\right]^{3-}$ exhibits linkage isomerism

E. $ \mathrm{NO}_2^{-}$and $\mathrm{SCN}^{-}$ligands are NOT ambidentate ligands

Choose the correct answer from the options given below :

A

A, B, C, D and E

B

B, C and D only

C

A, C and D only

D

A, C and E only

4
JEE Main 2026 (Online) 5th April Evening Shift
MCQ (Single Correct Answer)
+4
-1
Change Language

$$ \text { Match List - I with List - II. } $$

List - I
Purification technique
List - II
Used to separate
A. Simple distillation I. Steam volatile compound
B. Fractional distillation II. Two liquids with large difference in boiling points
C. Steam distillation III. Liquid decomposing at its boiling point
D. Distillation under reduced pressure IV. Two liquids with close boiling points

Choose the correct answer from the options given below :

A

A-II, B-III, C-I, D-IV

B

A-II, B-IV, C-I, D-III

C

A-II, B-IV, C-III, D-I

D

A-IV, B-III, C-II, D-I

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