Given below are two statements :
Statement (I): The correct sequence of bond lengths in the following species is :
$\ce{O2^{+}} < \ce{O2} < \ce{O2^{-}} < \ce{O2^{2-}}$
Statement (II): The correct sequence of number of unpaired electrons in the following species is :
$\ce{O2} > \ce{O2^{+}} > \ce{O2^{-}} > \ce{O2^{2-}}$
In the light of the above statements, choose the correct answer from the options given below :
Consider the following data.
(i) $2\text{Al(s)} + 6\text{HCl(aq)} \rightarrow \text{Al}_2\text{Cl}_6\text{(aq)} + 3\text{H}_2\text{(g)} + 1200~\text{kJ/mol}$
(ii) $\text{H}_2\text{(g)} + \text{Cl}_2\text{(g)} \rightarrow 2\text{HCl(g)} + 164~\text{kJ/mol}$
(iii) $\text{HCl(g)} + \text{aq} \rightarrow \text{HCl(aq)} + 83~\text{kJ/mol}$
(iv) $\text{Al}_2\text{Cl}_6\text{(s)} + \text{aq} \rightarrow \text{Al}_2\text{Cl}_6\text{(aq)} + 663~\text{kJ/mol}$
The enthalpy of formation of anhydrous solid $\text{Al}_2\text{Cl}_6$ is :
19.5 g of fluoro acetic acid (molar mass = 78 g mol−1) is dissolved in 500 g of water at 298 K. The depression in the freezing point of water was 1∘C. What is $K_a$ of fluoro acetic acid?
(For water, $K_f = 1.86$ K kg mol−1). Assume molarity and molality to have same values.
The solubility product constants of $\mathrm{Ag_2CrO_4}$ and $\mathrm{AgBr}$ are $32x$ and $4y$ respectively at 298 K.
The value of $$\left( \frac{\text{molarity of } \mathrm{Ag_2CrO_4}}{\text{molarity of } \mathrm{AgBr}} \right)$$ can be expressed as :
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