For strong electrolyte $\Lambda_m$ increases slowly with dilution and can be represented by the equation

$$\Lambda_m = \Lambda_m^\circ - A c^{1/2}$$

Molar conductivity values of the solutions of strong electrolyte AB at 18°C are given below :

The value of constant A based on the above data [in S cm² mol^-1/(mol/L)^1/2] unit is ________.

Two positively charged particles $m_1$ and $m_2$ have been accelerated across the same potential difference of 200 keV as shown below.

[Given mass of $m_1 = 1$ amu and $m_2 = 4$ amu]

The deBroglie wavelength of $m_1$ will be $x$ times of $m_2$. The value of $x$ is __________ (nearest integer)

A → B (first reaction)

C → D (second reaction)

Consider the above two first-order reactions. The rate constant for first reaction at 500 K is double of the same at 300 K. At 500 K, 50% of the reaction becomes complete in 2 hour. The activation energy of the second reaction is half of that of first reaction. If the rate constant at 500 K of the second reaction becomes double of the rate constant of first reaction at the same temperature; then rate constant for the second reaction at 300 K is _______ × 10^-1 hour^-1 (nearest integer).

Let the circle $x^2 + y^2 = 4$ intersect x-axis at the points A$(a, 0)$, $a > 0$ and B$(b, 0)$. Let $P(2 \cos \alpha, 2 \sin \alpha)$, $0 < \alpha < \frac{\pi}{2}$ and $Q(2 \cos \beta, 2 \sin \beta)$ be two points such that $(\alpha - \beta) = \frac{\pi}{2}$. Then the point of intersection of AQ and BP lies on :