Consider the elements N, P, O, S, Cl and F. The number of valence electrons present in the elements with most and least metallic character from the above list is respectively.

Observe the following equilibrium in a 1 L flask.

A(g) ⇌ B(g)

At T(K), the equilibrium concentrations of A and B are 0.5 M and 0.375 M respectively. 0.1 moles of A is added into the flask and heated to T(K) to establish the equilibrium again. The new equilibrium concentrations (in M) of A and B are respectively

The correct increasing order of spin-only magnetic moment values of the complex ions

[MnBr₄]²⁻ (A), [Cu(H₂O)₆]²⁺ (B), [Ni(CN)₄]²⁻ (C) and [Ni(H₂O)₆]²⁺ (D) is :

The correct order of acidic strength of the major products formed in the given reactions, is :

A. $\mathrm{PhNH}_2 \xrightarrow[\substack{\text { (2) } \mathrm{CuCN}^2 \\ \text { (3) } \mathrm{H}_3 \mathrm{O}^{+} / \Delta}]{\text { (1) } \mathrm{NaNO}_2+\mathrm{HCl}\left(<5^{\circ} \mathrm{C}\right)}[\mathrm{A}]$

B. $\mathrm{CH}_3 \mathrm{CH}_2 \mathrm{CHO} \xrightarrow[ \Delta]{\left[\mathrm{Ag}\left(\mathrm{NH}_3\right)_2\right]^{+}, \mathrm{OH}^{-}}[\mathrm{B}]$

C. $\mathrm{CH}_4+\mathrm{O}_2 \xrightarrow[\text { (ii) } \mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7 / \mathrm{H}^{+}]{\text {(i) } \mathrm{Mo}_2 \mathrm{O}_3}[\mathrm{C}]$

D. $\mathrm{PhCH}_2 \mathrm{MgBr}+\mathrm{CO}_2 \xrightarrow[\mathrm{H}_3 \mathrm{O}^{+}]{\text {Dry ether }}[\mathrm{D}]$

Choose the correct answer from the options given below :