The cyclic cations having the same number of hyperconjugation are :

Choose the correct answer from the options given below :

The number of isoelectronic species among $Sc^{3+}, Cr^{2+}, Mn^{3+}, Co^{3+}$ and $Fe^{3+}$ is ‘n’. If ‘n’ moles of AgCl is formed during the reaction of complex with formula $CoCl_3(en)_2NH_3$ with excess of $AgNO_3$ solution, then the number of electrons present in the $t_{2g}$ orbital of the complex is ________.

A volume of x mL of 5 M NaHCO₃ solution was mixed with 10 mL of 2 M H₂CO₃ solution to make an electrolytic buffer. If the same buffer was used in the following electrochemical cell to record a cell potential of 235.3 mV, then the value of x = ______ mL (nearest integer).

Sn(s) | Sn(OH)₆²⁻ (0.5 M) | HSnO₂⁻ (0.05 M) | OH⁻ | Bi₂O₃(s) | Bi(s)

Consider up to one place of decimal for intermediate calculations

For strong electrolyte $\Lambda_m$ increases slowly with dilution and can be represented by the equation

$$\Lambda_m = \Lambda_m^\circ - A c^{1/2}$$

Molar conductivity values of the solutions of strong electrolyte AB at 18°C are given below :

The value of constant A based on the above data [in S cm² mol^-1/(mol/L)^1/2] unit is ________.