Consider the following statements about manganate and permanganate ions. Identify the correct statements.

A. The geometry of both manganate and permanganate ions is tetrahedral.

B. The oxidation states of Mn in manganate and permanganate are +7 and +6, respectively.

C. Oxidation of Mn(II) salt by peroxodisulphate gives manganate ion as the final product.

D. Manganate ion is paramagnetic and permanganate ion is diamagnetic.

E. Acidified permanganate ion reduces oxalate, nitrite and iodide ions.

Choose the correct answer from the options given below :

The wavelength of photon 'A' is 400 nm. The frequency of photon 'B' is $10^{16} \ \text{s}^{-1}$. The wave number of photon 'C' is $10^4 \ \text{cm}^{-1}$. The correct order of energy of these photons is :

The reactions which produce alcohol as the product are :

A. $\mathrm{CH}_4 + \mathrm{O}_2 \xrightarrow{\mathrm{Mo}_2\mathrm{O}_3,\ \Delta} $

B. $2\mathrm{CH}_3\mathrm{CH}_3 + 3\mathrm{O}_2 \xrightarrow{(\mathrm{CH}_3\mathrm{COO})_2\mathrm{Mn},\ \Delta} $

C. $(\mathrm{CH}_3)_3\mathrm{CH} \xrightarrow{\mathrm{KMnO}_4} $

D. $ 2\mathrm{CH}_4 + \mathrm{O}_2 \xrightarrow{\mathrm{Cu}/523\ \mathrm{K}/100 \ \mathrm{atm}.} $

E. $\mathrm{CH}_3-\mathrm{CH}=\mathrm{CH}-\mathrm{CH}_3 \xrightarrow{\mathrm{KMnO}_4/\mathrm{H}^+} $

Choose the correct answer from the options given below :

For the given reaction;

CaCO₃ + 2HCl → CaCl₂ + H₂O + CO₂

If 90 g CaCO₃ is added to 300 mL of HCl which contains 38.55% HCl by mass and has density 1.13 g mL⁻¹, then which of the following option is correct?

Given molar mass of H, Cl, Ca and O are 1, 35.5, 40 and 16 g mol⁻¹ respectively.