The osmotic pressure of a living cell is 12 atm at 300 K. The strength of sodium chloride solution that is isotonic with the living cell at this temperature is ________ g L-1. (Nearest integer)
Given : R = 0.08 L atm K-1 mol-1
Assume complete dissociation of NaCl
(Given: Molar mass of Na and Cl are 23 and 35.5 g mol-1 respectively.)
The first and second ionization constants of H2X are $2.5 \times 10^{-8}$ and $1.0 \times 10^{-13}$ respectively.
The concentration of ${X^{2-}}$ in $0.1\ \mathrm{M}$ H2X solution is ______ $\times 10^{-15}\ \mathrm{M}$. (Nearest Integer)
A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol−1) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is ______ × 10−2. (nearest integer)
[Given: Kb of the solvent = 5.0 K kg mol−1]
Assume the solution to be dilute and no association or dissociation of X takes place in solution.
MX is a sparingly soluble salt that follows the given solubility equilibrium at 298 K.
$\mathrm{MX}(\mathrm{s}) \rightleftharpoons \mathrm{M}^{+}(\mathrm{aq})+\mathrm{X}^{-}(\mathrm{aq}) ; \quad \mathrm{K}_{\mathrm{sp}}=10^{-10}$
If the standard reduction potential for M+ (aq) + e− → M(s) is
$\left(\mathrm{E}_{\mathrm{M}^{+} / \mathrm{M}}^{\ominus}\right)=0.79 \mathrm{~V}$, then the value of the standard reduction potential for the metal/metal insoluble salt electrode $\mathrm{E}_{\mathrm{X}^{-} / \mathrm{MX}(\mathrm{s}) / \mathrm{M}}^{\ominus}$ is ______ mV. (nearest integer)
[Given: $ \dfrac{2.303 RT}{F} = 0.059\ \text{V} $]
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