By usual analysis, 1.00 g of compound (X) gave 1.79 g of magnesium pyrophosphate. The percentage of phosphorus in compound (X) is : (nearest integer)

(Given, molar mass in g mol⁻¹: O = 16, Mg = 24, P = 31)

Given below are two statements :

Statement I : Crystal Field Stabilization Energy (CFSE) of [Cr(H₂O)₆]²⁺ is greater than that of [Mn(H₂O)₆]²⁺.

Statement II : Potassium ferricyanide has a greater spin-only magnetic moment than sodium ferrocyanide.

In the light of the above statements, choose the correct answer from the options given below :

Given below are two statements :

Statement I : The correct order in terms of bond dissociation enthalpy is Cl₂ > Br₂ > F₂ > I₂.

Statement II : The correct trend in the covalent character of the metal halides is [SnCl₄ > SnCl₂], [PbCl₄ > PbCl₂] and [UF₄ > UF₆].

In the light of the above statements, choose the correct answer from the options given below :

Decomposition of A is a first order reaction at T(K) and is given by  A(g) → B(g) + C(g).

In a closed 1 L vessel, 1 bar A(g) is allowed to decompose at T(K). After 100 minutes, the total pressure was 1.5 bar. What is the rate constant (in min⁻¹) of the reaction? (log 2 = 0.3)