A perfect gas ( 0.1 mol ) having $\overline{\mathrm{C}}_v=1.50 \mathrm{R}$ (independent of temperature) undergoes the above transformation from point 1 to point 4. If each step is reversible, the total work done (w) while going from point 1 to point 4 is $(-)$___________$J$ (nearest integer)

[Given: $\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$ ]

A sample of n -octane $(1.14 \mathrm{~g})$ was completely burnt in excess of oxygen in a bomb calorimeter, whose heat capacity is $5 \mathrm{~kJ} \mathrm{~K}^{-1}$. As a result of combustion reaction, the temperature of the calorimeter is increased by 5 K . The magnitude of the heat of combustion of octane at constant volume is__________ $\mathrm{kJ} \mathrm{mol}^{-1}$ (nearest integer).

The area of the region $\{(x, y):|x-y| \leq y \leq 4 \sqrt{x}\}$ is

Line $L_1$ of slope 2 and line $L_2$ of slope $\frac{1}{2}$ intersect at the origin O . In the first quadrant, $\mathrm{P}_1$, $P_2, \ldots, P_{12}$ are 12 points on line $L_1$ and $Q_1, Q_2, \ldots, Q_9$ are 9 points on line $L_2$. Then the total number of triangles, that can be formed having vertices at three of the 22 points $\mathrm{O}, \mathrm{P}_1, \mathrm{P}_2, \ldots, \mathrm{P}_{12}$, $\mathrm{Q}_1, \mathrm{Q}_2, \ldots, \mathrm{Q}_9$, is: