1
JEE Main 2025 (Online) 22nd January Morning Shift
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-1

The number of molecules/ions that show linear geometry among the following is __________.

$\mathrm{SO}_2, \mathrm{BeCl}_2, \mathrm{CO}_2, \mathrm{~N}_3^{-}, \mathrm{NO}_2, \mathrm{~F}_2 \mathrm{O}, \mathrm{XeF}_2, \mathrm{NO}_2^{+}, \mathrm{I}_3^{-}, \mathrm{O}_3$

2
JEE Main 2025 (Online) 22nd January Morning Shift
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Some $\mathrm{CO}_2$ gas was kept in a sealed container at a pressure of 1 atm and at 273 K . This entire amount of $\mathrm{CO}_2$ gas was later passed through an aqueous solution of $\mathrm{Ca}(\mathrm{OH})_2$. The excess unreacted $\mathrm{Ca}(\mathrm{OH})_2$ was later neutralized with 0.1 M of 40 mL HCl . If the volume of the sealed container of $\mathrm{CO}_2$ was $x$, then $x$ is ____________ $\mathrm{cm}^3$ (nearest integer). [Given : The entire amount of $\mathrm{CO}_2(\mathrm{~g})$ reacted with exactly half the initial amount of $\mathrm{Ca}(\mathrm{OH})_2$ present in the aqueous solution.]

3
JEE Main 2025 (Online) 22nd January Morning Shift
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In Carius method for estimation of halogens, 180 mg of an organic compound produced 143.5 mg of AgCl . The percentage composition of chlorine in the compound is _________ %. (Given : molar mass in $\mathrm{g} \mathrm{~mol}^{-1}$ of $\mathrm{Ag}: 108, \mathrm{Cl}: 35.5$ )

4
JEE Main 2025 (Online) 22nd January Morning Shift
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$\mathrm{A \rightarrow B}$

The molecule A changes into its isomeric form B by following a first order kinetics at a temperature of 1000 K . If the energy barrier with respect to reactant energy for such isomeric transformation is $191.48 \mathrm{~kJ} \mathrm{~mol}^{-1}$ and the frequency factor is $10^{20}$, the time required for $50 \%$ molecules of A to become B is __________ picoseconds (nearest integer). $\left[\mathrm{R}=8.314 \mathrm{~J} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}\right]$

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