The number of atomic orbitals from the following having 5 radial nodes is ___________.
$$7 \mathrm{s}, 7 \mathrm{p}, 6 \mathrm{s}, 8 \mathrm{p}, 8 \mathrm{d}$$
The sum of oxidation state of the metals in $$\mathrm{Fe}(\mathrm{CO})_{5}, \mathrm{VO}^{2+}$$ and $$\mathrm{WO}_{3}$$ is ___________.
The number of incorrect statements from the following is ___________.
A. The electrical work that a reaction can perform at constant pressure and temperature is equal to the reaction Gibbs energy.
B. $$\mathrm{E_{cell}^{\circ}}$$ cell is dependent on the pressure.
C. $$\frac{d E^{\theta} \text { cell }}{\mathrm{dT}}=\frac{\Delta_{\mathrm{r}} \mathrm{S}^{\theta}}{\mathrm{nF}}$$
D. A cell is operating reversibly if the cell potential is exactly balanced by an opposing source of potential difference.
Let O be the origin and OP and OQ be the tangents to the circle $$x^2+y^2-6x+4y+8=0$$ at the points P and Q on it. If the circumcircle of the triangle OPQ passes through the point $$\left( {\alpha ,{1 \over 2}} \right)$$, then a value of $$\alpha$$ is :