In Dumas method for the estimation of $\mathrm{N}_{2}$, the sample is heated with copper oxide and the gas evolved is passed over :

Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R)

Assertion (A): The first ionization enthalpy of $3 \mathrm{~d}$ series elements is more than that of group 2 metals

Reason (R): In 3d series of elements successive filling of d-orbitals takes place.

In the light of the above statements, choose the correct answer from the options given below :

A hydrocarbon ' $\mathrm{X}$ ' with formula $\mathrm{C}_{6} \mathrm{H}_{8}$ uses two moles of $\mathrm{H}_{2}$ on catalytic hydrogenation of its one mole. On ozonolysis, ' $\mathrm{X}$ ' yields two moles of methane dicarbaldehyde. The hydrocarbon ' $\mathrm{X}$ ' is:

Given below are two statements :

Statement I: Upon heating a borax bead dipped in cupric sulphate in a luminous flame, the colour of the bead becomes green

Statement II: The green colour observed is due to the formation of copper(I) metaborate

In light of the above statements, choose the most appropriate answer from the options given below :