$$Pt(s)|{H_2}(g)(1\,bar)|{H^ + }(aq)(1\,M)||{M^{3 + }}(aq),{M^ + }(aq)|Pt(s)$$

The $$\mathrm{E_{cell}}$$ for the given cell is 0.1115 V at 298 K when $${{\left[ {{M^ + }(aq)} \right]} \over {\left[ {{M^{3 + }}(aq)} \right]}} = {10^a}$$

The value of $$a$$ is ____________

Given : $$\mathrm{E_{{M^{3 + }}/{M^ + }}^\theta = 0.2}$$ V

$${{2.303RT} \over F} = 0.059V$$

The number of given orbitals which have electron density along the axis is _________

$$\mathrm{p_x,p_y,p_z,d_{xy},d_{yz},d_{xz},d_{z^2},d_{x^2-y^2}}$$

Total number of moles of AgCl precipitated on addition of excess of AgNO$$_3$$ to one mole each of the following complexes $$\mathrm{[Co(NH_3)_4Cl_2]Cl,[Ni(H_2O)_6]Cl_2,[Pt(NH_3)_2Cl_2]}$$ and $$\mathrm{[Pd(NH_3)_4]Cl_2}$$ is ___________.

Number of compounds giving (i) red colouration with ceric ammonium nitrate and also (ii) positive iodoform test from the following is ___________