Elevation in the boiling point for 1 molar solution of glucose is 2 K. The depression in the freezing point for 2 molal solution of glucose in the same solvent is 2 K. The relation between K_b and K_f is

What will be the major product in the following mononitration reaction ?

An aromatic compound 'A' having molecular formula C₇H₆O₂ on treating with aqueous ammonia and heating forms compound 'B'. The compound 'B' on reaction with molecular bromine and potassium hydroxide provides compound 'C' having molecular formula C₆H₇N.. The structure of 'A' is

The difference in the number of unpaired electrons of a metal ion in its high spin and low-spin octahedral complexes is two. The metal ion is :