5.1 g NH₄SH is introduced in 3.0 L evacuated flask at 327ºC. 30% of the solid NH₄SH decomposed to NH₃ and H₂S as gases . The Kp of the reaction at 327^oC is (R = 0.082 L atm mol^–1 K^–1, Molar mass of S = 32 g mol^–1 molar mass of N = 14 g mol^–1)

The correct match between item 'I' and item 'II' is :

Item 'I' (compound)		Item 'II' (reagent)
(A)	Lysine	(P)	1-naphthol
(B)	Furfural	(Q)	ninhydrin
(C)	Benzylalcohol	(R)	KMnO4
(D)	Styrene	(S)	Ceric ammonium nitrate

An ideal gas undergoes isothermal compression from 5m³ to 1 m³ against a constant external pressure of 4 Nm^–2. Heat released in this process is used to increase the temperature of 1 mole of Al. If molar heat capacity of Al is 24 J mol^–1 K^–1, the temperature of Al increases by :

Elevation in the boiling point for 1 molar solution of glucose is 2 K. The depression in the freezing point for 2 molal solution of glucose in the same solvent is 2 K. The relation between K_b and K_f is