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1

JEE Main 2019 (Online) 12th January Morning Slot

MCQ (Single Correct Answer)
The major product of the following reaction is –

A
B
C
D

Explanation



DIBAL-H will reduce cyanides and esters to aldehydes.
2

JEE Main 2019 (Online) 11th January Evening Slot

MCQ (Single Correct Answer)
A compound 'X' on treatment with Br2/NaOH, provided C3H9N, which gives positive carbylamine test. Compound 'X' is :
A
CH3CH2CH2CONH2
B
CH3CON(CH3)2
C
CH3CH2COCH2NH
D
CH3COCH2NHCH3

Explanation

Br2/NaOH(Hoffman Hypobromide reagent) converts amide into primary amine having one carbon atom less, which gives carbylamine test. In the Amide there should be
-CONH2 group to produce primary amine.
3

JEE Main 2019 (Online) 10th January Evening Slot

MCQ (Single Correct Answer)
An aromatic compound 'A' having molecular formula C7H6O2 on treating with aqueous ammonia and heating forms compound 'B'. The compound 'B' on reaction with molecular bromine and potassium hydroxide provides compound 'C' having molecular formula C6H7N.. The structure of 'A' is
A
B
C
D

Explanation

4

JEE Main 2019 (Online) 10th January Morning Slot

MCQ (Single Correct Answer)
The major product of the following reaction is

A
B
C
D

Explanation



Alcoholic KOH performs $$\alpha $$ - $$\beta $$ elimination with halides.

The carbon which is attached to Br atom is called $$\alpha $$ carbon.

Here, two $$\alpha $$ carbon presents. Let's call them $$\alpha $$1 and $$\alpha $$2.

In case of $$\alpha $$1 carbon, H elimination can take place either from $$\beta $$1 or $$\beta $$2 carbon. But as we know always more stable product is formed from a reaction. Here if H is removed from $$\beta $$1 carbon then a $$\pi $$ bond is created which will perticipate in resonance with benzene ring and product will be more stable. But if H is removed from $$\beta $$2 carbon then the created $$\pi $$ bond will not perticipate in resonance with benzene ring so product will be less stable.

In case of $$\alpha $$2 carbon, H elimination can take place either from $$\beta $$2 or $$\beta $$3 carbon. But as we know always more stable product is formed from a reaction. Here if H is removed from $$\beta $$2 carbon then a $$\pi $$ bond is created which will perticipate in resonance with the $$\pi $$ bond associated with the $$\alpha $$1 carbon so product will be more stable. But if H is removed from $$\beta $$3 carbon then the created $$\pi $$ bond will not perticipate in any resonance so product will be less stable.

Questions Asked from Compounds Containing Nitrogen

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