The major product formed in the following reaction is

Compound $$\mathrm{P}$$ is neutral, $$\mathrm{Q}$$ gives effervescence with $$\mathrm{NaHCO}_{3}$$ while $$\mathrm{R}$$ reacts with Hinsbergs reagent to give solid soluble in $$\mathrm{NaOH}$$. Compound $$\mathrm{P}$$ is

In the following reaction, 'A' is

An organic compound $[\mathrm{A}]\left(\mathrm{C}_{4} \mathrm{H}_{11} \mathrm{~N}\right)$, shows optical activity and gives $\mathrm{N}_{2}$ gas on treatment with $\mathrm{HNO}_{2}$. The compound $[\mathrm{A}]$ reacts with $\mathrm{PhSO}_{2} \mathrm{Cl}$ producing a compound which is soluble in $\mathrm{KOH}$. The structure of $\mathrm{A}$ is :