Match List I with List II.
List I | List II | ||
---|---|---|---|
(A) | Benzenesulphonyl chloride | (I) | Test for primary amines |
(B) | Hoffmann bromamide reaction | (II) | Anti Saytzeff |
(C) | Carbylamine reaction | (III) | Hinsberg reagent |
(D) | Hoffmann orientation | (IV) | Known reaction of Isocyanates. |
Choose the correct answer from the options given below:
The correct sequential order of the reagents for the given reaction is
The correct stability order of the following diazonium salt is
Given below are two statements : one is labelled as Assertion (A) and the other is labelled as Reason (R).
Assertion (A) : Experimental reaction of $$\mathrm{CH}_{3} \mathrm{Cl}$$ with aniline and anhydrous $$\mathrm{AlCl}_{3}$$ does not give $$o$$ and $$p$$-methylaniline.
Reason (R): The $$-\mathrm{NH}_{2}$$ group of aniline becomes deactivating because of salt formation with anhydrous $$\mathrm{AlCl}_{3}$$ and hence yields $$m$$-methyl aniline as the product.
In the light of the above statements, choose the most appropriate answer from the options given below :