Considering the basic strength of amines in aqueous solution, which one has the smallest pK_b value?

A compound with molecular mass 180 is acylated with CH₃COCl to get a compound with molecular mass 390. The number of amino groups present per molecule of the former compound is:

The gas leaked from a storage tank of the Union Carbide plant in Bhopal gas tragedy was:

An organic compound A upon reacting with $$N{H_3}$$ gives $$B.$$ On heating $$B$$ gives $$C.$$ $$C$$ in presence of $$KOH$$ reacts with $$B{r_2}$$ to given $$C{H_3}C{H_2}N{H_2}2.$$ $$A$$ is :