1
JEE Main 2023 (Online) 6th April Evening Shift
Numerical
+4
-1

The equilibrium composition for the reaction $$\mathrm{PCl}_{3}+\mathrm{Cl}_{2} \rightleftharpoons \mathrm{PCl}_{5}$$ at $$298 \mathrm{~K}$$ is given below:

$$\left[\mathrm{PCl}_{3}\right]_{\mathrm{eq}}=0.2 \mathrm{~mol} \mathrm{~L}^{-1},\left[\mathrm{Cl}_{2}\right]_{\mathrm{eq}}=0.1 \mathrm{~mol} \mathrm{~L}^{-1},\left[\mathrm{PCl}_{5}\right]_{\mathrm{eq}}=0.40 \mathrm{~mol} \mathrm{~L}^{-1}$$

If $$0.2 \mathrm{~mol}$$ of $$\mathrm{Cl}_{2}$$ is added at the same temperature, the equilibrium concentrations of $$\mathrm{PCl}_{5}$$ is __________ $$\times 10^{-2} \mathrm{~mol} \mathrm{~L}^{-1}$$

Given : $$\mathrm{K}_{\mathrm{c}}$$ for the reaction at $$298 \mathrm{~K}$$ is 20

2
JEE Main 2023 (Online) 1st February Morning Shift
Numerical
+4
-1

(i) $$\mathrm{X}(\mathrm{g}) \rightleftharpoons \mathrm{Y}(\mathrm{g})+\mathrm{Z}(\mathrm{g}) \quad \mathrm{K}_{\mathrm{p} 1}=3$$

(ii) $$\mathrm{A}(\mathrm{g}) \rightleftharpoons 2 \mathrm{~B}(\mathrm{g}) \quad \mathrm{K}_{\mathrm{p} 2}=1$$

If the degree of dissociation and initial concentration of both the reactants $$\mathrm{X}(\mathrm{g})$$ and $$\mathrm{A}(\mathrm{g})$$ are equal, then the ratio of the total pressure at equilibrium $$\left(\frac{p_{1}}{p_{2}}\right)$$ is equal to $$\mathrm{x}: 1$$. The value of $$\mathrm{x}$$ is _____________ (Nearest integer)

3
JEE Main 2023 (Online) 31st January Morning Shift
Numerical
+4
-1

For reaction : $$\mathrm{SO}_{2}(\mathrm{~g})+\frac{1}{2} \mathrm{O}_{2}(\mathrm{~g}) \rightleftharpoons \mathrm{SO}_{3}(\mathrm{~g})$$

$$\mathrm{K}_{\mathrm{p}}=2 \times 10^{12}$$ at $$27^{\circ} \mathrm{C}$$ and $$1 \mathrm{~atm}$$ pressure. The $$\mathrm{K}_{\mathrm{c}}$$ for the same reaction is ____________ $$\times 10^{13}$$. (Nearest integer)

(Given $$\mathrm{R}=0.082 \mathrm{~L} \mathrm{~atm} \mathrm{~K}^{-1} \mathrm{~mol}^{-1}$$)

4
JEE Main 2023 (Online) 30th January Evening Shift
Numerical
+4
-1
Consider the following equation:

$2 \mathrm{SO}_{2}(g)+\mathrm{O}_{2}(g) \rightleftharpoons 2 \mathrm{SO}_{3}(g), \Delta H=-190 \mathrm{~kJ}$

The number of factors which will increase the yield of $\mathrm{SO}_{3}$ at equilibrium from the following is _______.

A. Increasing temperature

B. Increasing pressure

C. Adding more $\mathrm{SO}_{2}$

D. Adding more $\mathrm{O}_{2}$